Describe Bronsted Lowry's theory of acids and bases

DIFFERENCE BETWEEN ACID AND BASE

Bronsted-Lowry's Theory of Acids and Bases:

  • The Bronsted-Lowry theory of acids and bases was proposed by Danish chemist Johannes Bronsted and British chemist Thomas Lowry in 1923. 
  • According to this theory, an acid is a substance that donates a proton (H+), and a base is a substance that accepts a proton. 
  • In other words, an acid is a proton donor and a base is a proton acceptor. 
  • This theory is a more general definition of acids and bases as it encompasses a broader range of compounds and reactions.
 

Describe Arrhenius's theory of acids and bases

 Arrhenius's Theory of Acids and Bases:

  • The Arrhenius theory of acids and bases was proposed by Swedish chemist Svante Arrhenius in 1887.
  • According to this theory, an acid is a substance that increases the concentration of hydrogen ions (H+) in a solution, and a base is a substance that increases the concentration of hydroxide ions (OH-) in a solution. 
  • This theory is based on the simple ionization of water, where water molecules dissociate into hydrogen ions (H+) and hydroxide ions (OH-)

Define acid and base

 
DIFFERENCE BETWEEN ACID AND BASE

Acid:

  • An acid is a chemical substance that has a sour taste and can react with other substances to form salts.
  • Acids can be found in everyday things like lemon juice, vinegar, and stomach acid.
  • Acids can be strong or weak, depending on their ability to donate hydrogen ions (H+) when dissolved in water.
  • Strong acids have a low pH value (less than 3.5), are highly reactive, and can be dangerous if not handled properly.
  • Acids are commonly used in industries to make fertilizers, dyes, and plastics.

Base:

  • A base is a chemical substance that has a bitter taste and can react with acids to form salts.
  • Bases can be found in everyday things like baking soda, antacids, and cleaning products.
  • Bases can be strong or weak, depending on their ability to accept hydrogen ions (H+) when dissolved in water.
  • Strong bases have a high pH value (greater than 10.5), are highly reactive, and can be dangerous if not handled properly.
  • Bases are commonly used in the production of soaps, detergents, and other cleaning products.

Define colloids and their types- a.iyophillic, b.iyophobic

 Define colloids and their types:

  • Colloids are mixtures of two or more substances in which one substance is dispersed evenly throughout the other substance. 
  • The particles of the dispersed substance are small enough to be dispersed evenly but are too large to be dissolved.

There are two main types of colloids: lyophilic and lyophobic.

a. Lyophilic colloids:

 Lyophilic colloids are mixtures in which the particles of the dispersed substance are attracted to the particles of the dispersion medium. This type of colloid is also known as a sol. An example of a lyophilic colloid is blood, which is a mixture of red blood cells, plasma, and other substances.

b. Lyophobic colloids:

 Lyophobic colloids are mixtures in which the particles of the dispersed substance are not attracted to the particles of the dispersion medium. This type of colloid is also known as a emulsion. An example of a lyophobic colloid is oil in water, where oil droplets are dispersed in water.

Applications of colloids

Applications of colloids:

  • Colloids have many practical applications in various fields, including medicine, food science, and materials science.
  • In medicine, colloids are used as intravenous fluids to replace blood volume in patients. 
  • In food science, colloids are used as thickeners, stabilizers, and emulsifiers to improve the texture and stability of food products.
  • In materials science, colloids are used to create nanomaterials, such as nanoparticles and nanofibers, which have unique properties that make them useful in a wide range of applications, such as electronics, energy storage.

Define mole and the concept of molarity and normality

 
MOLARITY AND NORMALITY FORMULAS

Define mole and the concept of molarity and normality:

  • The mole is a unit used in chemistry to measure the amount of a substance. 
  • One mole of a substance contains Avogadro's number of particles, which is approximately 6.02 x 10^23. 

  • Molarity is a unit of concentration that is defined as the number of moles of solute per liter of solution. 
  • It is commonly abbreviated as M and is expressed in moles per liter (mol/L). 

  • Normality is a unit of concentration that is defined as the number of equivalent weights of solute per liter of solution. 
  • It is commonly abbreviated as N and is expressed in equivalents per liter (eq/L).

MW & EW of acid, base, and salt

 MW & EW of acid, base, and salt:

  • An acid is a substance that donates hydrogen ions (H+) in a chemical reaction, while a base accepts H+ ions.
  • The strength of an acid or base is measured on a pH scale, ranging from 0 to 14, where 0 is the most acidic and 14 is the most basic.
  • Strong acids and bases completely dissociate in water, while weak acids and bases only partially dissociate.
  • Acids have a sour taste, while bases have a bitter taste and feel slippery to the touch.
  • Salts are formed by the reaction of an acid and a base, where the H+ ions from the acid react with the OH- ions from the base to form water, leaving behind a salt.
  • Salts are usually solid, crystalline compounds that are electrically neutral.
  • The pH of a salt solution depends on the relative strengths of the acid and base that were used to form it.
  • In chemistry, the term "equivalent weight" (EW) is used to describe the weight of a substance that can combine with or replace one mole of hydrogen ions.
  • (MW) refers to the sum of the atomic weights of all the atoms in a molecule.
  • The chemical properties of acids, bases, and salts are important in many areas of science, including biology, medicine, and environmental science.

Define molecular weight and equivalent weight

Define molecular weight and equivalent weight:

  • Molecular weight is the mass of one mole of a substance and is expressed in atomic mass units (amu) or grams per mole (g/mol).
  • It is determined by adding up the atomic masses of all the atoms in a molecule.
  • Equivalent weight, on the other hand, is the mass of a substance that reacts with one equivalent of another substance in a chemical reaction. 
  • Equivalent weight is related to the number of moles of a substance that react with one mole of another substance.
MOLECULAR WEIGTH AND EQUIVALENT WEIGTH

 

Define the mole concept

 Define the mole concept:

  • The mole concept is a unit used in chemistry to measure the amount of a substance. 
  • One mole of a substance is defined as the amount of a substance that contains the same number of entities as there are in 12 grams of carbon-12. 
  • The entities can be atoms, molecules, ions, or other particles.
  • The mole concept is used to calculate the number of particles in a given amount of a substance, as well as to convert between mass, moles, and number of particles. 
  • The mole is a convenient unit because it allows chemists to work with large numbers of particles without having to count each one individually.

Classification of solutions based on the physical state

Classification of solutions based on the physical state:

  • Solutions can be classified based on the physical state of the solvent and solute. 
  • There are three main types of solutions: solid-solid, liquid-liquid, and gas-liquid.

a. Solid-solid solutions: 

  • In a solid-solid solution, both the solvent and solute are in a solid state. 
  • This type of solution is also known as a solid solution. 
  • An example of a solid-solid solution is an alloy, such as brass, which is a mixture of copper and zinc.

b. Liquid-liquid solutions: 

  • In a liquid-liquid solution, both the solvent and solute are in a liquid state. 
  • This type of solution is also known as a homogeneous mixture. 
  • An example of a liquid-liquid solution is a mixture of water and ethanol.

c. Gas-liquid solutions:

  •  In a gas-liquid solution, the solvent is in a liquid state and the solute is in a gaseous state. 
  • This type of solution is also known as a heterogeneous mixture.
  • An example of a gas-liquid solution is carbonated water, where carbon dioxide gas is dissolved in water.

Define solution, solute, and solvent

 
SOLUTE  SOLUTION SOLVENT

Define solution, solute, and solvent:

  • A solution is a homogeneous mixture of two or more substances where one substance, called the solute, is dissolved in another substance, called the solvent. 
  • The solute is present in smaller amount compared to the solvent.
  • The solute and solvent are evenly mixed, and the properties of the solution are different from the properties of the individual substances.
  • In a solution, the solute particles are dispersed throughout the solvent, and they are too small to be seen individually. 
  • The solute particles are held together by the solvent particles, and they are free to move around and interact with each other. 
  • The concentration of the solute in a solution is expressed in various units, such as molarity, molality, and percent by weight.

Explaint the concept of oxidation and reduction

 
OXIDATION VS REDUCTION

Oxidation and Reduction:

  • Oxidation is a process where a substance loses electrons, while reduction is a process where a substance gains electrons.
  • Together, oxidation and reduction are called redox reactions.
  • Oxidation and reduction always occur together because when one substance loses electrons, another substance must gain those electrons.
  • In redox reactions, the substance that loses electrons is called the reducing agent, while the substance that gains electrons is called the oxidizing agent.
  • An oxidizing agent causes oxidation, while a reducing agent causes reduction.
  • The oxidation state of an atom in a molecule or ion describes how many electrons that atom has gained or lost compared to its neutral state.
  • In a redox reaction, the total number of electrons lost by the reducing agent must equal the total number of electrons gained by the oxidizing agent.
  • In many cases, redox reactions involve the transfer of hydrogen ions (H+) along with electrons.
  • Redox reactions are important in many biological processes, including respiration and photosynthesis.
  • Corrosion is an example of a redox reaction where metal is oxidized by oxygen in the air, forming metal oxides.

Types of chemical bonds with characteristics, a.ionic bond, b.covalent bond, c.coordinate covalent bond

Types of Chemical Bonds:

a. Ionic Bond:

  • An ionic bond is formed between two ions of opposite charge. This bond is characterized by the transfer of electrons from one atom to another.

b. Covalent Bond: 

  • A covalent bond is formed when two atoms share electrons. 
  • This bond is characterized by the sharing of electrons between the two atoms.

c. Coordinate Covalent Bond:

  •  A coordinate covalent bond, also known as a dative bond, is formed when one atom provides both electrons in the bond. 
  • This bond is characterized by the asymmetric sharing of electrons.

Define chemical bonding and electro theory of valency

 Chemical Bonding and Electro-Theory of Valency:

  • Chemical bonding is the process by which atoms are held together in molecules or ions.
  • The electro-theory of valency states that the chemical behavior of an element is determined by the number of electrons in its outermost energy level, or valence shell.
  • The number of electrons in the valence shell is referred to as the element's valency.
  • Elements with a valency of one or two tend to form ions by losing or gaining electrons, respectively, while elements with a valency of four or more tend to form covalent bonds by sharing electrons.

Define orbit & orbital, shapes of orbitals s,p,d,f

 Orbit and Orbital:

  • An orbit is the path that an electron follows as it moves around the nucleus of an atom.
  • An orbital is a mathematical representation of an electron's energy and wave-like behavior.
  • Orbitals are described by three quantum numbers: n, l, and m, which define the size, shape, and orientation of the orbital, respectively.
  • There are four main types of orbitals: s, p, d, and f, which differ in their shapes and energy levels.
  • The s orbitals are spherical in shape, while p orbitals are dumbbell-shaped, d orbitals are cloverleaf-shaped, and f orbitals are more complex and less well understood.
ORBITALS DIFFERENT SHAPES

 

Describe the electronic configuration elements upto atomic number 30

  • The electronic configuration of elements refers to the arrangement of electrons in the energy levels (or shells) surrounding the nucleus of an atom. 
  • The number of electrons in each shell is determined by the element's atomic number, which is equal to the number of protons in the nucleus. 
  • The first 20 elements have a simple electron configuration, which can be easily predicted using the Aufbau principle.

Electronic Configuration upto 30 Elements

  • Hydrogen (1 electron) - 1s1
  • Helium (2 electrons) - 1s2
  • Lithium (3 electrons) - 1s2 2s1
  • Beryllium (4 electrons) - 1s2 2s2
  • Boron (5 electrons) - 1s2 2s2 2p1
  • Carbon (6 electrons) - 1s2 2s2 2p2
  • Nitrogen (7 electrons) - 1s2 2s2 2p3
  • Oxygen (8 electrons) - 1s2 2s2 2p4
  • Fluorine (9 electrons) - 1s2 2s2 2p5
  • Neon (10 electrons) - 1s2 2s2 2p6
  • Sodium (11 electrons) - 1s2 2s2 2p6 3s1
  • Magnesium (12 electrons) - 1s2 2s2 2p6 3s2
  • Aluminum (13 electrons) - 1s2 2s2 2p6 3s2 3p1
  • Silicon (14 electrons) - 1s2 2s2 2p6 3s2 3p2
  • Phosphorus (15 electrons) - 1s2 2s2 2p6 3s2 3p3
  • Sulfur (16 electrons) - 1s2 2s2 2p6 3s2 3p4
  • Chlorine (17 electrons) - 1s2 2s2 2p6 3s2 3p5
  • Argon (18 electrons) - 1s2 2s2 2p6 3s2 3p6
  • Potassium (19 electrons) - 1s2 2s2 2p6 3s2 3p6 4s1
  • Calcium (20 electrons) - 1s2 2s2 2p6 3s2 3p6 4s2

 

The electron configuration for elements beyond atomic number 20 becomes more complex and is determined by the filling of the 3d and 4s subshells. Some of the elements and their electron configurations up to atomic number 30 are:

 

  • Scandium (21 electrons) - [Ar] 3d1 4s2
  • Titanium (22 electrons) - [Ar] 3d2 4s2
  • Vanadium (23 electrons) - [Ar] 3d3 4s2
  • Chromium (24 electrons) - [Ar] 3d5 4s1
  • Manganese (25 electrons) - [Ar] 3d5 4s2
  • Iron (26 electrons) - [Ar] 3d6 4s2
  • Cobalt (27 electrons) - [Ar] 3d7 4s2
  • Nickel (28 electrons) - [Ar] 3d8 4s2
  • Copper (29 electrons) - [Ar] 3d10 4s1
  • Zinc (30 electrons) - [Ar] 3d10 4s2

 

It is important to note that these electron configurations are only approximate and do not take into account the interactions between electrons, such as spin and electron.

Explain pauls exclusion principle

 
PAULI EXCLUSION PRINCIPLE

Pauli's Exclusion Principle:

  • The Pauli exclusion principle states that no two electrons in an atom can have the same set of quantum numbers.
  • This means that each orbital can only hold two electrons, with opposite spins.
  • The Pauli exclusion principle helps to explain the stability of atoms and their electronic configurations.
  • Without the exclusion principle, electrons would occupy the same orbital and would experience mutual repulsion, leading to an unstable atom.

Describe the concept of Hund's rule

 Hund's Rule:

  • Hund's rule states that when there are multiple orbitals of the same energy level, electrons will occupy each orbital with a single electron before any orbital has two electrons.
  • This results in an unpaired electron, which is important in determining the magnetic behavior of an atom.
  • Hund's rule helps to explain why some elements have unpaired electrons, which can have a significant effect on their chemical behavior.
  • Hund's rule is a key principle in understanding the electronic configurations of atoms and the behavior of molecules.

Define the concept of the Bohrs Atomic model

 Bohr's Atomic Model:

  • a. The Bohr atomic model was proposed by Niels Bohr in 1913.
  • The model proposed that electrons move around the nucleus in defined orbits and that the energy of an electron is proportional to its distance from the nucleus.
  • Bohr also proposed that electrons could only exist in specific orbits and that transitions between orbits were associated with the emission or absorption of light.
  • The Bohr model was a major step forward in our understanding of the structure of atoms and helped to lay the foundations of quantum mechanics.
  • Although the Bohr model is no longer considered to be a complete and accurate description of the atom, it is still useful in introductory chemistry courses.
BOHR_S ATOMIC MODEL

 

Explain the Aufbau principle with suitable electronic configuration examples

AUFBAU PRINCIPLE


Aufbau Principle:

  • The Aufbau principle states that electrons occupy the lowest energy orbitals first, and then successively fill higher energy orbitals.
  • This principle is used to predict the electronic configuration of an element.
  • Electrons are filled into orbitals in order of increasing energy until all electrons are accounted for.
  • For example, the electronic configuration of helium is 1s2, which means that the first two electrons occupy the 1s orbital.
  • The Aufbau principle is based on the idea that electrons will occupy the lowest energy available to them.